The Greb Group

Research

The Greb Research Group explores the influence of strong ligand effects on the reactivity and physicochemical properties of p-block elements to expand the usual reactivity and property profiles of the Earth's most common elements. By dramatically altering the electronic structure through structural constraint or enabling element-ligand cooperativity, new reaction pathways for activating small molecules are discovered. Subtle changes in the oxidation states of p-block elements are achieved by interplay with redox-active ligands (Electromerism). Further, the group pursues a systematic study of the concept of Lewis acidity using data-driven methods. State-of-the-art computational approaches parallel all synthetic projects conducted in our group.

Read more
Recently Published
N. Ansmann, J. H. Alberts, F. Hagen, I. E. Blaum, L. Greb:
Co-Ligand-Dependent Rh(I)–Si(IV) Interactions in Silicon Z-Type Complexes
Inorg. Chem. 2025, Accepted Manuscript.
N. Ansmann, M. Kerscher, L. Greb:
Pd(0)/Pd(II) Electromerism Triggered by Lewis Base Coordination to a Redox-Active Silicon Z-Type Ligand
Angew. Chem. Int. Ed. 2025, e202417581.
Openings

Internship, Bachelor, Master, PhD, and PostDoc applicants are welcome to contact Lutz Greb.