The Greb Group

Research

The Greb Research Group explores the influence of strong ligand effects on the reactivity and physicochemical properties of p-block elements to expand the usual reactivity and property profiles of the Earth's most common elements. By dramatically altering the electronic structure through structural constraint or enabling element-ligand cooperativity, new reaction pathways for activating small molecules are discovered. Subtle changes in the oxidation states of p-block elements are achieved by interplay with redox-active ligands (Electromerism). Further, the group pursues a systematic study of the concept of Lewis acidity using data-driven methods. State-of-the-art computational approaches parallel all synthetic projects conducted in our group.

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Recently Published
V. D. Hannibal, L. Greb:
A Terminal Germanium Oxido Dianion by Structural Constraints
J. Am. Chem. Soc. 2025, Accepted Manuscript.
S. Stigler, T. Thorwart, L. Greb, S. Inoue:
Aryl- and Silyl-Substituted Silyliumylidene Ions in the Hydrosilylation of CO<sub>2</sub>
ChemCatChem 2025, Accepted Manuscript.
L. You, N. Ansmann, L. Greb:
Inverting Palladium-Phosphorus Lewis Pair Formation: Phosphonium Acting as Z-Type Ligand
Angew. Chem. Int. Ed. 2025, e202519355.
Openings

Internship, Bachelor, Master, PhD, and PostDoc applicants are welcome to contact Lutz Greb.