The Greb Group

Research

The Greb Research Group explores the influence of strong ligand effects on the reactivity and physicochemical properties of p-block elements to expand the usual reactivity and property profiles of the Earth's most common elements. By dramatically altering the electronic structure through structural constraint or enabling element-ligand cooperativity, new reaction pathways for activating small molecules are discovered. Subtle changes in the oxidation states of p-block elements are achieved by interplay with redox-active ligands (Electromerism). Further, the group pursues a systematic study of the concept of Lewis acidity using data-driven methods. State-of-the-art computational approaches parallel all synthetic projects conducted in our group.

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Recently Published
P. Erdmann, L. M. Sigmund, M. Schmitt, T. Hähnel, L. B. Dittmer, L. Greb:
A Benchmark Study of DFT-Computed p-Block Element Lewis Pair Formation Enthalpies against Experimental Calorimetric Data.
ChemPhysChem 2024, Accepted Manuscript.
S. J. Kohl+, L . M. Sigmund+, M. Schmitt, L. Greb:
Nitrogen Monoxide and Calix[4]pyrrolato Aluminate: Structural Constraint Enabled NO Dimerization.
Chem. Sci. 2024, 15, 10803-10809.
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Openings

Internship, Bachelor, Master, PhD, and PostDoc applicants are welcome to contact Lutz Greb.